Sustained highway driving in July is the worst-case scenario for a cooling system. It runs at full load for hours without the recovery breaks that daily driving allows. Check the coolant level in the overflow reservoir when the engine is cold. More importantly, have the coolant tested — not just topped off. Coolant has a service life, and degraded coolant loses its ability to transfer heat efficiently. If yours is more than two or three years old, a flush and refill before a summer road trip is money well spent.
Squeeze the radiator hoses. They should feel firm but pliable. Hard, cracked, or spongy hoses are likely to fail under thermal stress. Check the radiator cap seal while you're there — a weak cap lowers the system's pressure rating and drops the effective boiling point of your coolant.